) Abstract: Two novel BODIPY dyes were disclosed, which contain the bulky substituent, [(4-dimesitylboryl)phenyl]ethynyl at 2- and 2,6-positions
The steric bulkiness of the boryl group is effective to suppress the intermolecular interaction in the solid state and thus these two compounds display intense fluorescence not only in solution but also in the solid state
In addition, the titration experiment of these two compounds were also conducted by the addition of n-Bu4NF
The binding of the fluoride ions with the boron center of the boryl groups resulted in fluorescence quenching, illustrating their potential uses for the fluorescence sensing of fluoride ions
Keywords: Solid-state emissive; BODIPY dyes; Fluorescent sensing 下载PDF阅读器 PDF全文下载: 初稿 ( 203 ) 作者简介: Fu Guangliang,(1986-), male, Master Student, Organic fluorescent materials
通信联系人: Zhao Cuihua(1976-), female,Professor, Organic fluorescent materials
【收录情况】 中国科技论文在线: 付光亮
Zhao Cuihua 2,* ( 1、 School of Chemistry and Chemical Engineering, Shandong University, JiNan 250100
) 摘要: Two novel BODIPY dyes were disclosed, which contain the bulky substituent, [(4-dimesitylboryl)phenyl]ethynyl at 2- and 2,6-positions
The steric bulkiness of the boryl group is effective to suppress the intermolecular interaction in the solid state and thus these two compounds display intense fluorescence not only in solution but also in the solid state
In addition, the titration experiment of these two compounds were also conducted by the addition of n-Bu4NF
The binding of the fluoride ions with the boron center of the boryl groups resulted in fluorescence quenching, illustrating their potential uses for the fluorescence sensing of fluoride ions
关键词: Solid-state emissive; BODIPY dyes; Fluorescent sensing Fu Guangliang 1,
2、 School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100
赵以红等
一种基于三芳基硼的BODIPY染料:光学性质以及对F-的荧光识别[EB/OL]